Brad Pitt & Angelina Jolie: Photos Of The Former Couple

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April 13, 2012 4:28PM EDT

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Brad Pitt & Angelina Jolie

Brad Pitt & Angelina Jolie — For over a decade, it seemed as if ‘Brangelina’ would be a Hollywood romance that had a happy ending. Though Brad Pitt and Angelina Jolie’s romance started under particular circumstances – with them falling in love on the set of 2005’s ‘Mr. & Mrs. Smith’ while he was still married with Jennifer Aniston – their loved seemed legit.

Over the following twelve years, Brad and Angie would grow their family by adopting Zahara in 2006 and Pax in 2007. She gave birth to Shiloh in 2006 and twins Vivienne and Knox in 2008. Brad Pitt would also adopt Angelina’s first adopted child, son Maddox, in early 2006. After all this, Brad and Angie decided to take the plunge and get married. The couple was married in August 2014 at their estate in France.

Unfortunately, this love story would not have a happy ending. The couple separated in September 2016, with Jolie citing irreconcilable differences. She also requested physical custody of their children. In the following years since their breakup, Brad and Angie would have a war of words in the courts, nearly wiping away twelve years of happy memories. As these two learn to live without each other, view some of the happier moments of their romance.

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Brad Pitt & Angelina Jolie In ‘Mr. & Mrs. Smith’

Brad Pitt & Angelina Jolie In ‘Mr. & Mrs. Smith’ — The movie that started it all! Brad and Angelina starred in ‘Mr. & Mrs. Smith’ in 2005, playing secret agents trying to assisinate one another. It was a commercial success and brought together the two stars! But the film has since grown in infamy not because of its narrative, but because of the behind-the-scenes drama that captivated millions.

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Brad Pitt & Angelina Jolie’s Palpable Chemistry

Brad Pitt & Angelina Jolie’s Palpable Chemistry — In this memorable scene from ‘Mr. & Mrs. Smith,’ Brad and Angelina have a daring dance. The chemistry was almost too hot to handle! Furthremore, the pair’s working relationship translated to something more serious off screen, with the pair becoming infatuated with one another despite Brad still being married to ‘Friends’ star Jennifer Aniston at the time of filming.

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Brad Pitt & Angelina Jolie Land In Hot Water

Brad Pitt & Angelina Jolie Land In Hot Water — Prior to the film’s June 2005 release, Brad and Jen announced their split and their divorce was later finalized by October of that year. Meanwhile, Angelina was forced to fend off rumors that she and Brad had made their relationship physical off set, vehemently denying that Brad ever cheated on Jen with her.

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Brad Pitt & Angelina Jolie Are A Couple

Brad Pitt & Angelina Jolie Are A Couple — Brad Pitt and Angelina Jolie depart their plane on Jan. 28, 2006. They were coming back from the World Economic Forum. One year after his divorce from Jen, Brad wasn’t shy about showing off his new love with Angelina. The two were seen together, heading to events and supporting one another in new endeavors, but they rarely spoke about courtship, as Hollywood was still in shock.

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Brad Pitt and Angelina Jolie in Mumbai

Brad Pitt and Angelina Jolie in Mumbai — Brad Pitt with Maddox and Angelina Jolie with daughter Zahara in November 2006. Angelina Jolie was in India working as a UNHCR Goodwill Ambassador and filming her movie ‘A Mighty Heart’, a film based on slain American journalist Daniel Pearl. Brad joined Angelina in adopting Zahara and Maddox, making himself legaly their father and, in so doing, committing himself to Angie.

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Brad Pitt & Angelina Jolie Make A Red Carpet Appearance

Brad Pitt & Angelina Jolie Make A Red Carpet Appearance — Brad Pitt and Angelina Jolie on the red carpet of The 64th Annual Golden Globe Awards on Jan. 15, 2007. They truly were the hottest couple on the red carpet. Although they rarely spoke about their romance and personal lives with the press, the couple did let the world know that they were still going strong by attending a number of events together. The 64th Annual Golden Globe Awards was just one of the first of many.

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Angelina Jolie Shows Her Support For Brad’s Work

Angelina Jolie Shows Her Support For Brad’s Work — Angelina Jolie and Brad Pitt attending the ‘Ocean’s Thirteen’ film premiere presented by Warner Bros in Hollywood on June 5, 2007. The couple looked smoking hot in their all black ensembles. Much like awards shows, premieres were no different for these two, who regurlarly made public appearances together in support of their work.

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Brad Pitt Supports Angelina Jolie At The Premiere Of ‘Beowulf’

Brad Pitt Supports Angelina Jolie At The Premiere Of ‘Beowulf’ — Brad Pitt and Angelina Jolie at the European Premiere of ‘Beowulf’ at the Vue Westend on Nov. 11, 2007. The two posed for photos before the screening. As two of the hottest stars of their generation, Brad and Angie were essentially on equally playing field when it came to their work. Like Angie, Brad appeared to support his partner for her films, as well.

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Brad Pitt & Angelina Jolie Attend The 14th Annual Screen Actors Guild Awards

Brad Pitt & Angelina Jolie Attend The 14th Annual Screen Actors Guild Awards — Angelina Jolie and Brad Pitt at the 14th Annual Screen Actors Guild Awards on Jan. 27, 2008. They posed for photos prior to the awards ceremony. Being an A-list couple meant showing up for a number of major industry events. At the 2008 Screen Actors Guild Awards, however, Angelina was nominated for Outstanding Performance by a Female Actor in a Leading Role for her work in ‘A Mighty Heart.’ It was a special moment for the pair, with Brad supporting his partner despite her loss.

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Brad Pitt & Angelina Jolie Expecting Their First Biological Child

Brad Pitt & Angelina Jolie Expecting Their First Biological Child — Angelina Jolie, left, and Brad Pitt arrive for the premiere of the film “Kung Fu Panda” during the 61st International film festival in Cannes. Angie was pregnant with the couple’s first biological child, Shiloh. By this point, the couple already shared their three adopted children. Now, the two prepared for their first adventure together as biological parents to Shiloh.

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Brad Pitt & Angelina Jolie Attending The 14th Annual Critics’ Choice Awards

Brad Pitt & Angelina Jolie Attending The 14th Annual Critics’ Choice Awards — Angelina Jolie and Brad Pitt on the red carpet of the 14th Annual Critics’ Choice Awards on Jan. 8, 2009. They shared a sweet, intimate moment on the red carpet. Now, it was Angie’s turn to support her beau, as Brad was nominated for two awards for Best Actor and Best Acting Ensemble for ‘The Curious Case of Benjamin Button.’ The moment also marked nearly one year since the couple welcomed their twins, Vivienne and Knox.

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Brad Pitt & Angelina Jolie Take Their Love Overseas

Brad Pitt & Angelina Jolie Take Their Love Overseas — Brad Pitt and Angelina Jolie at the ‘Inglourious Basterds’ red carpet premiere at the 62nd Cannes Film Festival on May 20, 2009. The couple looked great together. Fans know already that Angie and Brad’s love was known widely on the international stage, but even at major industry events like Cannes, they showed a united front of support. Here, Angie was on hand to show Brad just how proud of him she was when his film with director Quentin Tarantino — ‘Inglourious Basterds’ — premiered at the Cannes Film Festival.

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Brad Pitt & Angelina Jolie Still Going Strong

Brad Pitt & Angelina Jolie Still Going Strong — Angelina Jolie and Brad Pitt at ‘The Tourist’ film premiere in New York on Dec. 6, 2010. The pair looked great for the event! The December 2010 prmiere marked roughly five years since the couple started dating, in a post-‘Mr. & Mrs. Smith’ world. With six children together, they appeared happier than ever, and were one of contemporary Hollywood’s golden couples.

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Brad Pitt & Angelina Jolie At The 68th Annual Golden Globe Awards

Brad Pitt & Angelina Jolie At The 68th Annual Golden Globe Awards — Angelina Jolie and Brad Pitt at the 68th Annual Golden Globe Awards on Jan. 16, 2011. Angie glistened in her gorgeous emerald green gown and Brad looked so cool in his sunglasses. Confirming their A-list status among the Hollywood elite, time didn’t stop them from continuing to make appearances together at major industry events. In fact, the two continued to attend many of the award season functions, offering a hand to hold and a shoulder to lay their weary head.

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Brad Pitt & Angelina Jolie As Hollywood’s Golden Couple

Brad Pitt & Angelina Jolie As Hollywood’s Golden Couple — Angelina Jolie and Brad Pitt depart the screening of ‘The Tree of Life’ at the 64th international film festival in Cannes. They held hands while walking down the red carpeted stairs. Not only in their attendance to major industry events were Brad and Angie considered a golden couple, but by the early 2010s it was so clear that these two had a romantic partnership that was incredibly steady. At the time, it didn’t seem like anything could break them.

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Angelina Jolie With Brad Pitt During An Injury

Angelina Jolie With Brad Pitt During An Injury — Angelina Jolie and Brad Pitt at The 69th Annual Golden Globe Awards on Jan. 15, 2012. Angie looked so regal as Brad used a cain to help him move around. Although they weren’t married until years later, Brad and Angie clearly held the vows ‘in sickness and in health’ to heart. Not only did they support each other’s career pursuits, but clearly in times of need. Just look at them holding hands.

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Brad Pitt & Angelina Jolie As Refined Couples’ Goals

Brad Pitt & Angelina Jolie As Refined Couples’ Goals — Angelina Jolie and Brad Pitt arrive for the premiere of the movie ‘In the Land of Blood and Honey’ during the 62nd Berlin International Film Festival in Berlin on Feb. 11, 2012. They both looked so lovely together. The two were always the hot topic of Hollywood, but by 2012, they really defined themselves as the regal Hollywood royalty that they are. Beyond supporting their creative endeavors, the two continued to show off their love in ways that fit their roles. In fact, they reunited on screen for another of Angie’s directorial efforts a few years later in 2015 with the couple’s film ‘By The Sea,’ which ultimately foreshadowed the pair’s downfall.

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Brad Pitt & Angelina Jolie Prove They’ve Still Got It

Brad Pitt & Angelina Jolie Prove They’ve Still Got It — Brad Pitt and Angelina Jolie arrive for the 84th Annual Academy Awards at the Hollywood and Highland Center in Hollywood on Feb. 26, 2012. Angie looked fierce in her black gown. By this point in their relationship, it was clear that Brad Angie were a committed pair, but fans didn’t expect them to show off their youthfulness full force. At the 84th Oscars, Angie showed off her leg in a black gown that left jaws on the floor, but it merely confirmed to supporters of the couple that, while they were widely known as ‘BrAngelina,’ they were very much their own person.

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Brad Pitt & Angelina Jolie As Parents

Brad Pitt & Angelina Jolie As Parents — Brad Pitt, Angelina Jolie, Shiloh Jolie-Pitt, and Pax Jolie-Pitt at LAX airport on Feb. 5, 2014. The family appeared to be departing for travel. Brad and Angie had some of the busiest schedules in Hollywood. Between industry events, acting, directing, and producing, and more, they still managed to be active participants in their children’s lives — a feat that is far more complicated than many of their fans will likely ever know!

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Brad Pitt & Angelina Jolie In Their Final Years

Brad Pitt & Angelina Jolie In Their Final Years — Angelina Jolie and Brad Pitt arrive on the red carpet for the 2014 Ee British Academy Film Awards Ceremony at the Royal Opera House in London on Feb. 16, 2014. They both looked great in their suits! By 2014, Brad and Angelina finally decided to tie the knot, but their marriage wouldn’t last long. Unfortunately, it marked a turning point for the couple who would go from being Hollywood’s pinacle pair to splitting spouses.

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Brad Pitt & Angelina Jolie At One Of Their Final Public Appearances

Brad Pitt & Angelina Jolie At One Of Their Final Public Appearances — Brad Pitt and Angelina Jolie pose for photographers as they arrive for the ‘Maleficent’ exhibit in Kensington Gardens, in west London, on May 8, 2014. Brad was so supportive of Angie! Not long after the two attended the event, they announced their separation in 2016. What ensude was a complicated, at times volatile divorce with Angie seeking primary custody of their children. Eventually things did seem to calm down between the pair as they got closer to a final custody decision. But this marked the last chapter in the Brad and Angie saga.

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